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Er3+/Tm3+ codoped tellurite glass for blue upconversion-Structure, thermal stability and spectroscopic properties

Identifieur interne : 000400 ( Main/Exploration ); précédent : 000399; suivant : 000401

Er3+/Tm3+ codoped tellurite glass for blue upconversion-Structure, thermal stability and spectroscopic properties

Auteurs : DANDAN YIN [République populaire de Chine] ; YAWEI QI [République populaire de Chine] ; SHENGXI PENG [République populaire de Chine] ; SHICHAO ZHENG [République populaire de Chine] ; FEN CHEN [République populaire de Chine] ; GAOBO YANG [République populaire de Chine] ; XUNSI WANG [République populaire de Chine] ; YAXUN ZHOU [République populaire de Chine]

Source :

RBID : Pascal:14-0191327

Descripteurs français

English descriptors

Abstract

The Er3+/Tm3+ codoped WO3 modified tellurite glasses with molar composition of (75-x)TeO2-20ZnO- 5Na2O-xWO3-0.2 wt%Er2O3-0.8 wt%Tm2O3 (x=0,4,8,12 mol%) were prepared to realize the blue upconversion emission. The absorption spectra, visible upconversion spectra and 1.53 μm band fluorescence spectra of glass samples were measured, together with the quantitative calculations of relevant spectroscopic parameters of Tm3+ and energy transfer micro-parameters between Er3+ and Tm3+ ions, to evaluate the effects of WO3 oxide on the spectroscopic properties of Er3+-Tm3+ ions. It was found that the introduction of WO3 oxide can further improve the blue upconversion emission of Tm3+ through an enhanced phonon-assisted energy transfer process. Meanwhile, with the increase of WO3 amount, the thermal stability of glass hosts, characterized by the difference between the glass crystallization onset temperature and the transition temperature which obtained from the measured differential scanning calorimeter (DSC) curves, increased and no obvious crystallization peak was detected when the WO3 amount increased to 12 mol%. Furthermore, the glass structure was briefly analyzed with the obtained Judd-Ofelt intensity parameters, the measured Raman spectra and X-ray diffraction (XRD) curves. The present results demonstrate the feasibility of realizing strong blue upconversion emission by introducing WO3 oxide with high phonon energy into the Er3+/Tm3+ codoped tellurite glass and also indicate its potential application as a glass host applied for the blue upconversion lasers.


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Le document en format XML

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codoped tellurite glass for blue upconversion-Structure, thermal stability and spectroscopic properties</title>
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<sup>+</sup>
/Tm
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codoped tellurite glass for blue upconversion-Structure, thermal stability and spectroscopic properties</title>
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<name sortKey="Shichao Zheng" sort="Shichao Zheng" uniqKey="Shichao Zheng" last="Shichao Zheng">SHICHAO ZHENG</name>
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<name sortKey="Yaxun Zhou" sort="Yaxun Zhou" uniqKey="Yaxun Zhou" last="Yaxun Zhou">YAXUN ZHOU</name>
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<series>
<title level="j" type="main">Journal of luminescence</title>
<title level="j" type="abbreviated">J. lumin.</title>
<idno type="ISSN">0022-2313</idno>
<imprint>
<date when="2014">2014</date>
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<title level="j" type="main">Journal of luminescence</title>
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<idno type="ISSN">0022-2313</idno>
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<keywords scheme="KwdEn" xml:lang="en">
<term>Absorption spectra</term>
<term>Calcium nitride</term>
<term>Codoping</term>
<term>Energy transfer</term>
<term>Erbium oxides</term>
<term>Fluorescence</term>
<term>Frequency conversion</term>
<term>Phonons</term>
<term>Photoluminescence</term>
<term>Structure stability</term>
<term>Tellurite glass</term>
<term>Tellurium oxide</term>
<term>Thermal stability</term>
<term>Thulium oxides</term>
<term>Tungsten oxide</term>
<term>Visible spectra</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Codopage</term>
<term>Conversion fréquence</term>
<term>Stabilité structurale</term>
<term>Stabilité thermique</term>
<term>Photoluminescence</term>
<term>Spectre absorption</term>
<term>Oxyde de tungstène</term>
<term>Oxyde de tellure</term>
<term>Oxyde d'erbium</term>
<term>Oxyde de thulium</term>
<term>Spectre visible</term>
<term>Fluorescence</term>
<term>Transfert énergie</term>
<term>Nitrure de calcium</term>
<term>Phonon</term>
<term>WO3</term>
<term>TeO2</term>
<term>Er2O3</term>
<term>Verre de tellurite</term>
</keywords>
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<front>
<div type="abstract" xml:lang="en">The Er
<sup>3+</sup>
/Tm
<sup>3+</sup>
codoped WO
<sub>3</sub>
modified tellurite glasses with molar composition of (75-x)TeO
<sub>2</sub>
-20ZnO- 5Na
<sub>2</sub>
O-xWO
<sub>3</sub>
-0.2 wt%Er
<sub>2</sub>
O
<sub>3</sub>
-0.8 wt%Tm
<sub>2</sub>
O
<sub>3</sub>
(x=0,4,8,12 mol%) were prepared to realize the blue upconversion emission. The absorption spectra, visible upconversion spectra and 1.53 μm band fluorescence spectra of glass samples were measured, together with the quantitative calculations of relevant spectroscopic parameters of Tm
<sup>3+</sup>
and energy transfer micro-parameters between Er
<sup>3+</sup>
and Tm
<sup>3+</sup>
ions, to evaluate the effects of WO
<sub>3</sub>
oxide on the spectroscopic properties of Er
<sup>3+</sup>
-Tm
<sup>3+</sup>
ions. It was found that the introduction of WO
<sub>3</sub>
oxide can further improve the blue upconversion emission of Tm
<sup>3+</sup>
through an enhanced phonon-assisted energy transfer process. Meanwhile, with the increase of WO
<sub>3</sub>
amount, the thermal stability of glass hosts, characterized by the difference between the glass crystallization onset temperature and the transition temperature which obtained from the measured differential scanning calorimeter (DSC) curves, increased and no obvious crystallization peak was detected when the WO
<sub>3</sub>
amount increased to 12 mol%. Furthermore, the glass structure was briefly analyzed with the obtained Judd-Ofelt intensity parameters, the measured Raman spectra and X-ray diffraction (XRD) curves. The present results demonstrate the feasibility of realizing strong blue upconversion emission by introducing WO
<sub>3</sub>
oxide with high phonon energy into the Er
<sup>3+</sup>
/Tm
<sup>3+</sup>
codoped tellurite glass and also indicate its potential application as a glass host applied for the blue upconversion lasers.</div>
</front>
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<country>
<li>République populaire de Chine</li>
</country>
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<noRegion>
<name sortKey="Dandan Yin" sort="Dandan Yin" uniqKey="Dandan Yin" last="Dandan Yin">DANDAN YIN</name>
</noRegion>
<name sortKey="Fen Chen" sort="Fen Chen" uniqKey="Fen Chen" last="Fen Chen">FEN CHEN</name>
<name sortKey="Gaobo Yang" sort="Gaobo Yang" uniqKey="Gaobo Yang" last="Gaobo Yang">GAOBO YANG</name>
<name sortKey="Shengxi Peng" sort="Shengxi Peng" uniqKey="Shengxi Peng" last="Shengxi Peng">SHENGXI PENG</name>
<name sortKey="Shichao Zheng" sort="Shichao Zheng" uniqKey="Shichao Zheng" last="Shichao Zheng">SHICHAO ZHENG</name>
<name sortKey="Xunsi Wang" sort="Xunsi Wang" uniqKey="Xunsi Wang" last="Xunsi Wang">XUNSI WANG</name>
<name sortKey="Xunsi Wang" sort="Xunsi Wang" uniqKey="Xunsi Wang" last="Xunsi Wang">XUNSI WANG</name>
<name sortKey="Yawei Qi" sort="Yawei Qi" uniqKey="Yawei Qi" last="Yawei Qi">YAWEI QI</name>
<name sortKey="Yaxun Zhou" sort="Yaxun Zhou" uniqKey="Yaxun Zhou" last="Yaxun Zhou">YAXUN ZHOU</name>
</country>
</tree>
</affiliations>
</record>

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